Crystal structure of bis{N-[2-(dimethylamino)ethyl]quinolin-8-amine-κ3 N,N′,N′′}nickel(II) dichloride 3.5-hydrate
نویسندگان
چکیده
In the title compound, [Ni(C13H17N3)2]Cl2·3.5H2O, the geom-etry of the NiN6 complex cation is slightly distorted octa-hedral, with a facial arrangement of the two tridentate N-[2-(di--methyl-amino)-eth-yl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of two independent complex half-mol-ecules located on centres of inversion, together with two chloride counter-anions and 3.5 water mol-ecules of solvation, one of which is disordered across an inversion centre. In the crystal, O-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen-bonding inter-actions form a three-dimensional network structure.
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عنوان ژورنال:
دوره 70 شماره
صفحات -
تاریخ انتشار 2014